Silisão opened the goals in the 16th minute with a Marquinus header before Roberto Firmino scored twice in the 30th and 49th minutes.
Jose Carrasco scored by mistake in the 66th minute, and Felipe Coutinho completed the fifth with a header in the 79th minute.
In Colombia, Los Cafeteros did not find it difficult to beat their Venezuelan visitors to win 3 goals without response.
Duvan Zapata scored in the 16th minute and Luis Muriel, his teammate at Italian club Atalanta, scored in the 26th and 45th minutes.
Brazil jumped to the top of the qualifiers on goal difference from runner-up Colombia, third Uruguay and fourth, Argentina.
Brazil hosts Peru on Wednesday and Colombia plays host Chile.
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